In Salesforce Lightning Experience, the "Send through External Email Services" option allows users to send emails directly from Salesforce using their connected Gmail or Office 365 account. This feature provides a more seamless experience by routing outbound emails through the user's personal email provider rather than Salesforce's mail servers.
System administrators may not see this option in Setup if the org's email deliverability Access Level is not set to "All Email." This article explains how to make the option visible and enable the feature.
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