As Cross Object Filters are not available within Professional Edition, the best way to create a report that will display Accounts without Opportunities is by creating a Roll-Up Summary field on the Account Object that will display the number of associated opportunity records.
Create a Custom Roll-Up Summary field on the Account object
1. Click Reports | New Report
2. Select the Accounts Report type, then click Create
3. Select the All Accounts and Date fields per your requirements
4. Drag the Opportunity Count field in the filter and add the Criteria as Opportunity Count equals to 0.
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