In a fresh install, when added to the quote line's Line Editor field set, the field SBQQ__AdditionalDiscount__c on the Quote Line appears as two fields when selected. The field on the left allows for the entry of a number (to the precision defined in the "Unit Price Scale" field in the General Settings) and the field on the right is a picklist that allows the user to select a Percent discount or an Amount discount.
If a % discount is selected, the Quote Line field SBQQ__Discount__c populates with the user-defined value.
If an Amount discount is selected, the Quote Line field SBQQ__AdditionalDiscountAmount__c populates with the user-defined value.
CONSIDERATIONS
Note: your admin can include or exclude picklist values that directly impact how users are allowed to discount Quote Lines using the SBQQ__AdditionalDiscount__c in the Quote Line Editor. "Unit" and "Total" values may be added as additional picklist values within the Line Editor for the SBQQ__AdditionalDiscount__c field. See here for more information.
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