You can designate up to 25 External ID fields per object.
1. Make sure there are fewer than 25 External ID fields on the object.
2. If there are more than 25, you may need to log a case with Salesforce Support.
Notes:
1. Ask your administrator to log a case with Salesforce Support.
2. Provide your organization ID.
3. Explain the business need for increasing the limit on indexes.
4. Salesforce Support will review your request and current indexes, then action as needed.
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