When a contact record is saved without an associated Account, the system treats it as though the sharing settings are Private. This means that only the contact owner and those with View All Data or Modify All Data can search for it using Global Search or Lookup Search.
Option 1: Create a List View of Contacts without Accounts
In this scenario, a List View on the Contacts object, with the filter criteria of 'Account Name' 'equals' <blank> will generate a list of Contacts without Accounts.
Option 2: Use the Data Loader to export the Contacts without Accounts
Since your goal may be to export the records into a spreadsheet, the best way to do this is to use the Data Loader in the following way.
This will generate a list of Contacts that do not link to any accounts. This is the best way to ensure that an Account link does not exist for this Contact.
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