The 'Estimate your organization's code coverage' link estimates your code coverage and isn't 100% accurate.
Below are ways to check the reliability of the 'Estimate your organization's code coverage' option.
We can use Tooling API to calculate the coverage individually for an Apex class/Apex trigger or overall coverage.
If you are still not confident enough, then you can do a production validation (click 'Validate Only' button in the tool you are using to deploy) and it will show errors/warnings if there is no coverage for classes.
Testing and Code Coverage
Code coverage best practices
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