Two routing options are available for Chat buttons in Salesforce: 'Reroute Declined Chat Requests to Available Agents' and 'Automatically Accept Chats After They're Assigned to an Agent'. These options appear only when the Routing Type is set to 'Least Active' or 'Most Available'.
Add Chat Routing Options.
https://help.salesforce.com/s/articleView?id=service.live_agent_chat_routing_options.htm&type=5
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