Salesforce Administrators may find that it is not possible to set the Content record type preferences for profiles when you Assign Record Types and Page Layouts in the Enhanced Profile User Interface because the Content Version object is not available when you perform a Search in the Enhanced Profile User Interface.
Note: It is not possible to assign Content Version record types to permission sets and is only possible through Profiles.
Option 1: Temporarily disable the "Enable Enhanced Profile User Interface" setting as outlined in the Enable the Enhanced Profile User Interface documentation:
Option 2: Manually construct the URL to the desired setup section:
How is record type access specified?
Content upload fails or displays 'An error has occurred'
Assign Record Types or Page Layouts in Profiles
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